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KMID : 1039220180280020200
Journal of Korean Society of Occupational and Environmental Hygiene
2018 Volume.28 No. 2 p.200 ~ p.210
Exposure to Ozone and TVOCs during Shipyard Welding and the Adequacy of RPE
Han Don-Hee

Kim Dong-Hwan
Abstract
Objectives: The purpose of this study is to assess the exposure to ozone and total volatile organic compounds (TVOCs) generated during welding work at a shipyard and recommend respiratory protective equipment (RPE) adequate against these hazards.

Method: Ozone was collected for about 30 minutes at two-minutes intervals using a direct reading instrument, specifically an ozone analyzer (Serinus 10, Ecotech, Australia). TVOCs were collected for about 30 minutes at three-minute intervals using a portable GC (Alpha 115, Synspec BV, the Netherlands), and were determined simultaneously by area sampling at the welding plume closest to the welder¡¯s breathing zone. The total measurements were 162 for ozone (CO2 welding 47, TIG 60, stick 55), and 136 for TVOCs (CO2 65, TIG 50, stick 21). Based on these measurements, a literature survey was conducted to assess the adequacy of RPE.

Results: Relative to Korean OEL, measurements above STEL 0.2 ppm were 23.4% for CO2, 63.3% for TIG and 14.5% for stick welding. There were significant differences (p=<0.0001) among welding types. Compared with ACGIH peak exposure of 0.4 ppm for ozone, which is not applied in Korea, CO2 welding exceeded it by 10.6%, TIG by 40.0% and stick by 7.3%. Although it was not feasible to compare them directly since there are no Korean OEL, TVOCs had very high levels similar to the concentrations before moving into a new apartment and about 10-20 times the indoor air quality recommendations for some individual measurements.

Conclusions: As ozone removal RPE has been recommended in welding environments for a long time (Lunau, 1967), this fact was demonstrated based on the results of the on-site work environment measurements (ozone and TVOCs). In conclusion, for all welding at a shipyard, gas/vapor and particulate combination RPE are recommended. If this is not possible, it should at least be present for TIG welding.
KEYWORD
Ozone, RPE, shipyard, TVOCs, welding
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